This paper is divided in two sections. The first section present the measurement and evaluation of soiling effects of spectral light and solar transmittance decay of Ethylene Tetrafluoroethylene Copolymer (ETFE) membranes after three and six months of exposure in Milano city outdoor urban conditions, with different tilt and orientation. The obtained values where use to compute thermal and solar properties of a multilayer ETFE panel. The second section presents the results of an experimental campaign for measuring thermal transmittance of a non-pneumatic and non-cushion shape double layer ETFE sample panel realized with two membranes parallel to each other and tensioned on a frame. The thermal transmittance measurement reflects ISO 9869 measurement approach combined with the use of a thermographic camera to evaluate surface temperatures over the sample panel.