ENEA-IRIS Open Archive è l’archivio della produzione scientifica dell'ENEA, realizzato con l'obiettivo di raccogliere, catalogare e rendere facilmente accessibili in rete i risultati della ricerca. Gli autori dell’ENEA provvedono a depositare le proprie pubblicazioni (articoli su rivista, presentazioni a congressi, report, ecc.). In particolare, quelle finanziate dalla Commissione Europea nell’ambito del programma H2020 (che prevede il deposito obbligatorio in un Repository), una volta caricate, vengono automaticamente importate dal portale europeo OpenAIRE. È possibile inserire, o importare direttamente dalle banche dati previste, le informazioni descrittive del documento e anche allegare, ove consentito dalla normativa sul diritto d'autore, il testo completo della pubblicazione.

ENEA-IRIS Open Archive utilizza la piattaforma IRIS (Institutional Research Information System) sviluppata da CINECA.

The aim of this work is to investigate how SO2 can affect MCFC performance and to discover the possible mechanisms involved in cathode sulphur poisoning, specifically considering the possible use of MCFCs in CCS (Carbon Capture and Storage) application. The different contributions of cathodic, anodic and electrolyte reactions have been considered to get a complete picture of the evolution of performance degradation. Experimental tests have been performed at the Fuel Cell Centre laboratories of Korea Institute of Science and Technology (KIST) thanks to 100 cm2 single cell facilities and comparing results using both an optimized gas for laboratory conditions and a gas composition that simulates MCFCs when running in a Natural Gas Combined Cycle (NGCC) power plant. Polarisation curves, endurance tests, impedance measurements and gas analyses have been carried out to support the investigation. Copyright © 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

Experimental analysis of SO2 effects on Molten Carbonate Fuel Cells

McPhail, S.J.
2014-01-01

Abstract

The aim of this work is to investigate how SO2 can affect MCFC performance and to discover the possible mechanisms involved in cathode sulphur poisoning, specifically considering the possible use of MCFCs in CCS (Carbon Capture and Storage) application. The different contributions of cathodic, anodic and electrolyte reactions have been considered to get a complete picture of the evolution of performance degradation. Experimental tests have been performed at the Fuel Cell Centre laboratories of Korea Institute of Science and Technology (KIST) thanks to 100 cm2 single cell facilities and comparing results using both an optimized gas for laboratory conditions and a gas composition that simulates MCFCs when running in a Natural Gas Combined Cycle (NGCC) power plant. Polarisation curves, endurance tests, impedance measurements and gas analyses have been carried out to support the investigation. Copyright © 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
2014
Fuel contaminants;Poisoning mechanism;Performance decay;Molten Carbonate Fuel Cells;Sulphur dioxide
4.1 Contributo in Atti di convegno
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.12079/5758
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
social impact