In this work, carbon nanomaterials have been prepared by CVD technology onto alumina substrates, coated by nanosized Co-catalyst at different thickness (2.5 nm and 7.5 nm) and used for a simple gas sensor device. The surface has been functionalized with sputtered Pt-nanocluster at a tuned loading of 8, 15 and 30 nm. The response of the chemiresistors in terms of p-type electrical conductance has been investigated as a function of the thickness of the Pt-nanoclusters towards different gases (NO 2, NH 3, CO, CH 4, CO 2). Furthermore, the effect of the temperature ranging from 20°C to 250°C on the sensor response has been addressed as well. Additionally, a short-term stability of the carbon nanomaterials based sensor towards NO 2 gas detection has been investigated for a 2-month period. The gas sensors based on Pt-modified carbon nanomaterials exhibit higher sensitivity compared to unmodified material, fast response, reversibility, repeatability, moderate drift of the baseline signal, sub-ppm range detection limit. © 2012 Springer Science+Business Media, LLC.
Tuned sensing properties of metal-modified carbon-based nanostructures layers for gas microsensors
Rossi R.;Alvisi M.;Cassano G.;Pentassuglia R.;Dimaio D.;Suriano D.;Serra E.;Piscopiello E.;Pfister V.;Penza M.
2012-01-01
Abstract
In this work, carbon nanomaterials have been prepared by CVD technology onto alumina substrates, coated by nanosized Co-catalyst at different thickness (2.5 nm and 7.5 nm) and used for a simple gas sensor device. The surface has been functionalized with sputtered Pt-nanocluster at a tuned loading of 8, 15 and 30 nm. The response of the chemiresistors in terms of p-type electrical conductance has been investigated as a function of the thickness of the Pt-nanoclusters towards different gases (NO 2, NH 3, CO, CH 4, CO 2). Furthermore, the effect of the temperature ranging from 20°C to 250°C on the sensor response has been addressed as well. Additionally, a short-term stability of the carbon nanomaterials based sensor towards NO 2 gas detection has been investigated for a 2-month period. The gas sensors based on Pt-modified carbon nanomaterials exhibit higher sensitivity compared to unmodified material, fast response, reversibility, repeatability, moderate drift of the baseline signal, sub-ppm range detection limit. © 2012 Springer Science+Business Media, LLC.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
