The valorization of CO2 via renewable energy sources allows one to obtain carbon-neutral fuels through its hydrogenation, like methane. In this study, Ni0.05 Ce0.95 O2−δ catalysts were prepared using a simple one-pot hydrothermal method yielding nanorod and nanocube particles to be used for the methanation reaction. Samples were characterized by XRD, BET, TEM, H2-TPR, and H2-TPD experiments. The catalytic activity tests revealed that the best performing catalyst was Ni0.05 Ce0.95 O2−δ, with nanorod morphology, which gave a CO2 conversion of 40% with a selectivity of CH4 as high as 93%, operating at 325◦ C and a GHSV of 240,000 cm3 h−1 g−1 . However, the lower activation energy was found for Ni0.05 Ce0.95 O2−δ catalysts with nanocube morphology. Furthermore, an in operando diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) analysis was performed flowing CO2:H2 or CO:H2 mixture, showing that the main reaction pathway, for the CO2 methanation, is the direct hydrogenation of formate intermediate.
One-pot synthesis of ni0.05 ce0.95 o2−δ catalysts with nanocubes and nanorods morphology for co2 methanation reaction and in operando drift analysis of intermediate species
Luisetto I.;Stendardo S.;
2021-01-01
Abstract
The valorization of CO2 via renewable energy sources allows one to obtain carbon-neutral fuels through its hydrogenation, like methane. In this study, Ni0.05 Ce0.95 O2−δ catalysts were prepared using a simple one-pot hydrothermal method yielding nanorod and nanocube particles to be used for the methanation reaction. Samples were characterized by XRD, BET, TEM, H2-TPR, and H2-TPD experiments. The catalytic activity tests revealed that the best performing catalyst was Ni0.05 Ce0.95 O2−δ, with nanorod morphology, which gave a CO2 conversion of 40% with a selectivity of CH4 as high as 93%, operating at 325◦ C and a GHSV of 240,000 cm3 h−1 g−1 . However, the lower activation energy was found for Ni0.05 Ce0.95 O2−δ catalysts with nanocube morphology. Furthermore, an in operando diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) analysis was performed flowing CO2:H2 or CO:H2 mixture, showing that the main reaction pathway, for the CO2 methanation, is the direct hydrogenation of formate intermediate.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
